Theory explains how new material could improve electronic shelf life

ScienceDaily (Jan. 9, 2012) — Research by UT Dallas engineers could lead to more-efficient cooling of electronics, producing quieter and longer-lasting computers, and cellphones and other devices.

Much of modern technology is based on silicon's use as a semiconductor material, but research recently published in the journal Nature Materials shows that graphene conducts heat about 20 times faster than silicon.

"Heat is generated every time a device computes," said "Dr. Kyeongjae "KJ" Cho, associate professor of materials science and engineering and physics at UT Dallas and one of the paper's authors. "For example a laptop fan pumps heat out of the system, but heat removal starts with a chip on the inside. Engineered graphene could be used to remove heat -- fast."

It was demonstrated in 2004 that graphite could be changed into a sheet of bonded carbon atoms called graphene, which is believed to be the strongest material ever measured. Although much research has focused on the strength and electronics of the material, Cho has been studying its thermal conductivity.

As electronics become more complex and decrease in size, the challenge to remove heat from the core becomes more difficult, he said. Desktop and laptop computers have fans.

Smaller electronic devices such as cellphones have other thermoelectric cooling devices.

"The performance of an electronic device degrades as it heats up, and if it continues the device fails," said Cho, also a visiting professor at Seoul National University in South Korea.

"The faster heat is removed, the more efficient the device runs and the longer it lasts."

Research assistant Hengji Zhang of UT Dallas is also an author of the paper. Cho and Zhang have published prior papers in the Journal of Nanomaterials and Physical Review B about graphene's thermal conductivity. For the Nature Materials paper, researchers at UT Austin conducted an experiment about graphene's heat transfer. They used a laser beam to heat the center of a portion of graphene, then measured the temperature difference from the middle of the graphene to the edge. Cho's theory helped explain their findings.

"We refined our modeling work taking into account their experimental conditions and found we have quantitative agreement," Cho said. "By understanding how heat transfers through a two-dimensional graphene system, we can further manipulate its use in semiconductor devices used in everyday life." For this purpose, Cho and Zhang are preparing a follow-up article on how to control the thermal conductivity in graphene.

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Theory explains how new material could improve electronic shelf life

ScienceDaily (Jan. 9, 2012) — Research by UT Dallas engineers could lead to more-efficient cooling of electronics, producing quieter and longer-lasting computers, and cellphones and other devices.

Much of modern technology is based on silicon's use as a semiconductor material, but research recently published in the journal Nature Materials shows that graphene conducts heat about 20 times faster than silicon.

"Heat is generated every time a device computes," said "Dr. Kyeongjae "KJ" Cho, associate professor of materials science and engineering and physics at UT Dallas and one of the paper's authors. "For example a laptop fan pumps heat out of the system, but heat removal starts with a chip on the inside. Engineered graphene could be used to remove heat -- fast."

It was demonstrated in 2004 that graphite could be changed into a sheet of bonded carbon atoms called graphene, which is believed to be the strongest material ever measured. Although much research has focused on the strength and electronics of the material, Cho has been studying its thermal conductivity.

As electronics become more complex and decrease in size, the challenge to remove heat from the core becomes more difficult, he said. Desktop and laptop computers have fans.

Smaller electronic devices such as cellphones have other thermoelectric cooling devices.

"The performance of an electronic device degrades as it heats up, and if it continues the device fails," said Cho, also a visiting professor at Seoul National University in South Korea.

"The faster heat is removed, the more efficient the device runs and the longer it lasts."

Research assistant Hengji Zhang of UT Dallas is also an author of the paper. Cho and Zhang have published prior papers in the Journal of Nanomaterials and Physical Review B about graphene's thermal conductivity. For the Nature Materials paper, researchers at UT Austin conducted an experiment about graphene's heat transfer. They used a laser beam to heat the center of a portion of graphene, then measured the temperature difference from the middle of the graphene to the edge. Cho's theory helped explain their findings.

"We refined our modeling work taking into account their experimental conditions and found we have quantitative agreement," Cho said. "By understanding how heat transfers through a two-dimensional graphene system, we can further manipulate its use in semiconductor devices used in everyday life." For this purpose, Cho and Zhang are preparing a follow-up article on how to control the thermal conductivity in graphene.

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New material can enhance energy, computer, lighting technologies

ScienceDaily (Nov. 16, 2011) — Arizona State University researchers have created a new compound crystal material that promises to help produce advances in a range of scientific and technological pursuits.

ASU electrical engineering professor Cun-Zheng Ning says the material, called erbium chloride silicate, can be used to develop the next generations of computers, improve the capabilities of the Internet, increase the efficiency of silicon-based photovoltaic cells to convert sunlight into electrical energy, and enhance the quality of solid-state lighting and sensor technology.

Ning's research team of team of students and post-doctoral degree assistants help synthesize the new compound in ASU's Nanophotonics Lab in the School of Electrical, Computer and Energy Engineering, one of the university's Ira A. Fulton Schools of Engineering.

The lab's erbium research is supported by the U.S. Army Research Office and U.S. Air Force Office of Scientific Research. Details about the new compound are reported in the Optical Materials Express on the website of the Optical Society of America.

The breakthrough involves the first-ever synthesis of a new erbium compound in the form of a single-crystal nanowire, which has superior properties compared to erbium compounds in other forms.

Erbium is one of the most important members of the rare earth family in the periodic table of chemical elements. It emits photons in the wavelength range of 1.5 micrometers, which are used in the optical fibers essential to high-quality performance of the Internet and telephones.

Erbium is used in doping optical fibers to amplify the signal of the Internet and telephones in telecommunications systems. Doping is the term used to describe the process of inserting low concentrations of various elements into other substances as a way to alter the electrical or optical properties of the substances to produce desired results. The elements used in such processes are referred to as dopants.

"Since we could not dope as many erbium atoms in a fiber as we wish, fibers had to be very long to be useful for amplifying an Internet signal. This makes integrating Internet communications and computing on a chip very difficult," Ning explains.

"With the new erbium compound, 1,000 times more erbium atoms are contained in the compound. This means many devices can be integrated into a chip-scale system," he says. "Thus the new compound materials containing erbium can be integrated with silicon to combine computing and communication functionalities on the same inexpensive silicon platform to increase the speed of computing and Internet operation at the same time."

Erbium materials can also be used to increase the energy-conversion efficiency of silicon solar cells.

Silicon does not absorb solar radiation with wavelengths longer than 1.1 microns, which results in waste of energy -- making solar cells less efficient.

Erbium materials can remedy the situation by converting two or more photons carrying small amounts of energy into one photon that is carrying a larger amount of energy. The single, more powerful photon can then be absorbed by silicon, thus increasing the efficiency of solar cells.

Erbium materials also help absorb ultraviolet light from the sun and convert it into photons carrying small amounts of energy, which can then be more efficiently converted into electricity by silicon cells. This color-conversion function of turning ultraviolet light into other visible colors of light is also important in generating white light for solid-state lighting devices.

While erbium's importance is well-recognized, producing erbium materials of high quality has been challenging, Ning says.

The standard approach is to introduce erbium as a dopant into various host materials, such as silicon oxide, silicon, and many other crystals and glasses.

"One big problem has been that we have not been able to introduce enough erbium atoms into crystals and glasses without degrading optical quality, because too many of these kinds of dopants would cluster, which lowers the optical quality," he says.

What is unique about the new erbium material synthesized by Ning's group is that erbium is no longer randomly introduced as a dopant. Instead, erbium is part of a uniform compound and the number of erbium atoms is a factor of 1,000 more than the maximum amount that can be introduced in other erbium-doped materials.

Increasing the number of erbium atoms provides more optical activity to produce stronger lighting. It also enhances the conversion of different colors of light into white light to produce higher-quality solid-state lighting and enables solar cells to more efficiently convert sunlight in electrical energy.

In addition, since erbium atoms are organized in a periodic array, they do not cluster in this new compound. The fact that the material has been produced in a high-quality single-crystal form makes the optical quality superior to the other doped materials, Ning says.

Like many scientific discoveries, the synthesis of this new erbium material was made somewhat by accident.

"Similar to what other researchers are doing, we were originally trying to dope erbium into silicon nanowires. But the characteristics demonstrated by the material surprised us," he says. "We got a new material. We did not know what it was, and there was no published document that described it. It took us more than a year to finally realize we got a new single-crystal material no one else had produced."

Ning and his team are now trying to use the new erbium compound for various applications, such as increasing silicon solar cell efficiency and making miniaturized optical amplifiers for chip-scale photonic systems for computers and high-speed Internet.

"Most importantly," he says, "there are many things we have yet to learn about what can be achieved with use of the material. Our preliminary studies of its characteristics show it has many amazing properties and superior optical quality. More exciting discoveries are waiting to be made."

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New revolutionary material can be worked like glass

ScienceDaily (Nov. 18, 2011) — A common feature of sailboards, aircraft and electronic circuits is that they all contain resins used for their lightness, strength and resistance. However, once cured, these resins can no longer be reshaped. Only certain inorganic compounds, including glass, offered this possibility until now. Combining such properties in a single material seemed impossible until a team led by Ludwik Leibler, CNRS researcher at the Laboratoire "Matière Molle et Chimie" (CNRS/ESPCI ParisTech), developed a new class of compounds capable of this remarkable feat. Repairable and recyclable, this novel material can be shaped at will and in a reversible manner at high temperature.

And, quite surprisingly, it also retains certain properties specific to organic resins and rubbers: it is light, insoluble and difficult to break. Inexpensive and easy to produce, this material could be used in numerous industrial applications, particularly in the automobile, aeronautics, building, electronics and leisure sectors. This work is published on 18 November 2011 in Science.

Replacing metals by lighter but just as efficient materials is a necessity for numerous industries, such as aeronautics, car manufacturing, building, electronics and sports industry. Due to their exceptional mechanical strength and thermal and chemical resistance, composite materials based on thermosetting resins are currently the most suitable. However, such resins must be cured in situ, using from the outset the definitive shape of the part to be produced. In fact, once these resins have hardened, welding and repair become impossible. In addition, even when hot, it is impossible to reshape parts in the manner of a blacksmith or glassmaker.

This is because glass (inorganic silica) is a unique material: once heated, it changes from a solid to a liquid state in a very progressive manner (glass transition), which means it can be shaped as required without using molds. Conceiving highly resistant materials that can be repaired and are infinitely malleable, like glass, is a real challenge both in economic and ecological terms. It requires a material that is capable of flowing when hot, while being insoluble and neither as brittle nor as "heavy" as glass.

From ingredients that are currently available and used in industry (epoxy resins, hardeners, catalysts, etc.), researchers from the Laboratoire "Matière Molle et Chimie" (CNRS/ESPCI ParisTech) developed a novel organic material made of a molecular network with original properties: under the action of heat, this network is capable of reorganizing itself without altering the number of cross-links between its atoms. This novel material goes from the liquid to the solid state or vice versa, just like glass. Until now, only silica and some inorganic compounds were known to show this type of behavior. The material thus acts like purely organic silica. It is insoluble even when heated above its glass transition temperature.

Remarkably, at room temperature, it resembles either hard or soft elastic solids, depending on the chosen composition. In both cases, it has the same characteristics as thermosetting resins and rubbers currently used in industry, namely lightness, resistance and insolubility. Most importantly, it has a significant advantage over the latter as it is reshapeable at will and can be repaired and recycled under the action of heat. This property means it can undergo transformations using methods that cannot be envisaged either for thermosetting resins or for conventional plastic materials. In particular, it makes it possible to produce shapes that are difficult or even impossible to obtain by molding or for which making a mold is too expensive for the envisaged purpose.

Used as the basis of composites, this new material could therefore favorably compete with metals and find extensive applications in sectors as diverse as electronics, car manufacturing, construction, aeronautics or printing. In addition to these applications, these results shed unexpected light on a fundamental problem: the physics of glass transition.

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Journal Reference:

D. Montarnal, M. Capelot, F. Tournilhac, L. Leibler. Silica-Like Malleable Materials from Permanent Organic Networks. Science, 2011; 334 (6058): 965 DOI: 10.1126/science.1212648

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New X-ray technique for electronic structures: Ability to probe deep below material surfaces should be boon for nanoscale devices

ScienceDaily (Aug. 26, 2011) — The expression "beauty's only skin-deep" has often been applied to the chemistry of materials because so much action takes place at the surface. However, for many of the materials in today's high technologies, such as semiconductors and superconductors, once a device is fabricated it is the electronic structures below the surface, in the bulk of the material or in buried layers, that determine its effectiveness. For the past 30 years, one of the most valuable and widely used techniques for studying electronic structures has been ARPES -- Angle-Resolved PhotoEmission Spectroscopy. However, this technique primarily looks at surfaces.

Now, for the first time, bulk electronic structures have been opened to comparable scrutiny through a new variation of this standard called HARPES -- Hard x-ray Angle-Resolved PhotoEmission Spectroscopy -- whose development was led by researchers with the U.S. Department of Energy (DOE)'s Lawrence Berkeley National Laboratory (Berkeley Lab).

"HARPES should enable us to study the electronic structure of any new material in the bulk, with minimum effects of surface reactions or contamination," says physicist Charles Fadley who led the development of HARPES. "Our technique should also allow us to probe the buried layers and interfaces that are ubiquitous in nanoscale devices, and are key to smaller logic elements in electronics, novel memory architectures in spintronics, and more efficient energy conversion in such technologies as photovoltaic cells."

Fadley is a physicist who holds joint appointments with Berkeley Lab's Materials Sciences Division and the University of California (UC) Davis where he is a Distinguished Professor of Physics. He is also one of the world's foremost practitioners of photoelectron spectroscopy, a technique based on the photoelectric effect described in 1905 by Albert Einstein. When a beam of photons -- particles of light such as x-rays -- is flashed on a sample, energy is transferred from the photons to electrons, causing them to be emitted from the sample. By measuring the kinetic energy of these emitted photoelectrons and the angles at which they are ejected, scientists can learn much about the sample's electronic structure.

The successful demonstration of the HARPES technique has been reported in the journal Nature Materials in a paper titled "Probing bulk electronic structure with hard X-ray angle-resolved photoemission." Fadley was the senior author of this paper. The lead and corresponding author was Alexander Gray, a member of Fadley's UC Davis research group and also an affiliate with Berkeley Lab's Materials Sciences Division.

"The key to probing the bulk electronic structure is using hard x-rays, which are x-rays with sufficiently high photon energies to eject photoelectrons from deep beneath the surface of a solid material," Gray says. "High-energy photons impart high kinetic energies to the ejected photoelectrons, enabling them to travel longer distances within the solid. The result is that more of the signal originating from the bulk will be detected by the analyzer."

Whereas the typical ARPES experiment, using low energy or "soft" x-rays (10~100 eV photons), probes to a depth of less than 10 angstroms (a few layers of atoms), with their HARPES technique Fadley and Gray and their colleagues on this project were able to probe as deep as 60 Angstroms into the bulk of single crystals of tungsten and gallium-arsenide. Their achievement was made possible by a combination of third generation light sources capable of producing intense beams of hard x-rays, and an advanced electron spectrometer to measure energies and angles.

"While high-energy photons are needed to penetrate into the bulk, at high energies the photoemission intensity that carries information about the electronic band structure is drastically reduced by various factors, such as phonon effects and small photoelectric cross sections of the valence-band electron orbitals," Gray says. "However, HARPES measurements become possible with the advent of the third-generation synchrotron light sources and the development of hard x-ray monochromators and optics capable of focusing a highly intense x-ray beam into a very small measurement spot."

To demonstrate the capabilities of their HARPES technique, Fadley and Gray used a high intensity undulator beamline at the SPring8 synchrotron radiation facility in Hyogo, Japan, which is operated by the Japanese National Institute for Materials Sciences. The samples they worked with, tungsten and gallium arsenide, contain relatively heavy elements that have relatively small phonon effects (atomic vibrations) but to further reduce these effects the samples were cryo-cooled. By combining room temperature and cryo data, the researchers were able to correct for the influence of indirect transitions and photoelectron diffraction in their results.

"Having sufficient photons from the beamline was critical as was having a high energy resolution that required an undulator source and a special monochromator and a photoelectron spectrometer with both high throughput for intensity and a lens with angle-resolving capability," Fadley says.

Adds Gray, "Our HARPES technique not only provided us with information about the energies of the emitted photoelectrons, but also with information about the crystal momentum of electrons within the bulk solid. This extra dimension carries a vast amount of information regarding electronic, magnetic and structural properties of materials, and can be used for in-depth studies of such novel phenomena as high-temperature superconductivity and so-called Mott transitions from insulating to conducting states that might be used for logic switching in the future."

In the future, Fadley and Gray will be able to carry out HARPES experiments much closer to home. At Berkeley Lab's Advanced Light Source (ALS), the first of the world's third generation synchrotron radiation facilities, a new experimental chamber for beamline 9.3.1 is scheduled to open this fall that will provide unique hard x-ray angle-resolved photoemission capabilities.

Says Zahid Hussain, who manages the ALS Scientific Support group, "An additional hard x-ray photoemission spectroscopy chamber at beamline 9.3.1 will feature an ambient pressure high energy photoemission capability that will allow the study of energy related problems, such as batteries, fuel cells, and catalysis under in-situ and in-operando conditions. It will also enable depth-sensitive studies and make it possible to probe not only solid, but also gas and liquid interfaces. This will be the first such experimental facility in the world."

Co-authoring the Nature Materials paper with Fadley and Gray were Christian Papp, Shigenori Ueda, Benjamin Balke, Yoshiyuki Yamashita, Lukasz Plucinski, Jan Minár, Juergen Braun, Erik Ylvisaker, Claus Schneider, Warren Pickett, Hubert Ebert and Keisuke Kobayashi.

This research was supported in part by the DOE Office of Science.

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Journal Reference:

A. X. Gray, C. Papp, S. Ueda, B. Balke, Y. Yamashita, L. Plucinski, J. Minár, J. Braun, E. R. Ylvisaker, C. M. Schneider, W. E. Pickett, H. Ebert, K. Kobayashi, C. S. Fadley. Probing bulk electronic structure with hard X-ray angle-resolved photoemission. Nature Materials, 2011; DOI: 10.1038/nmat3089

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