Subtle electronic effect in magnetite discovered: Long-standing puzzle in study of magnetism finally solved

ScienceDaily (Dec. 21, 2011) — A fundamental problem that has long puzzled scientists has been solved after more than 70 years. An international team of researchers has discovered a subtle electronic effect in magnetite, the most magnetic of all naturally occurring minerals. The effect causes a dramatic change to how this material conducts electricity at very low temperatures.

The discovery gives new insight into the mineral in which magnetism was discovered, and it may enable magnetite and similar materials to be exploited in new ways.

Ancient knowledge

Magnetite's properties have been known for more than 2000 years and gave rise to the original concepts of magnets and magnetism. The mineral has formed the basis for decades of research into magnetic recording and information storage materials.

The research was led by the University in collaboration with the European Synchrotron Radiation Facility (ESRF) in Grenoble, France, where the experiments were conducted. Their results were published in Nature.

Unexplained behaviour

In 1939, Dutch scientist Evert Verwey discovered that the electrical conductivity of magnetite decreases abruptly and dramatically at low temperatures. At about 125 Kelvin, or minus 150 degrees Celsius, the metallic mineral turns into an insulator.

Despite many efforts, until now the reason for this transition has been debated and remained controversial.

X-ray experiment

The team of scientists fired an intense X-ray beam at a tiny crystal of magnetite at very low temperatures. Their results enabled them to understand a subtle rearrangement of the mineral's chemical structure. Electrons are trapped within groups of three iron atoms, where they can no longer transport an electrical current.

"We have solved a fundamental problem in understanding the original magnetic material, upon which everything we know about magnetism is built," said Professor Paul Attfield, Centre for Science at Extreme Conditions. "This vital insight into how magnetite is constructed and how it behaves will help in the development of future electronic and magnetic technologies."

The research was funded by the Science and Technology Facilities Council, the Engineering and Physical Sciences Research Council, and the Leverhulme Trust.

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The above story is reprinted from materials provided by University of Edinburgh.

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Journal References:

Mark S. Senn, Jon P. Wright, J. Paul Attfield. Charge order and three-site distortions in the Verwey structure of magnetite. Nature, 2011; DOI: 10.1038/nature10704J. Paul Attfield. Condensed-matter physics: A fresh twist on shrinking materials. Nature, 2011; 480 (7378): 465 DOI: 10.1038/480465a

Note: If no author is given, the source is cited instead.

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